Collapse of metastability : dynamics of first-order phase transition / Seiji Miyashita.

Author
Miyashita, Seiji [Browse]
Format
Book
Language
English
Published/​Created
  • Singapore : Springer, [2022]
  • ©2022
Description
1 online resource (260 pages)

Details

Subject(s)
Series
Bibliographic references
Includes bibliographical references and index.
Source of description
Description based on print version record.
Contents
  • Intro
  • Preface
  • Contents
  • 1 Introduction
  • 1.1 Concept of Metastability
  • 1.1.1 Life Time of a Metastable State
  • Part I Metastability in Classical Systems
  • 2 Metastability in Thermodynamic Systems
  • 2.1 Introduction
  • 2.2 Mean-Field Theory for a Ferromagnetic Ising System
  • 2.2.1 Self-consistent Equation of the Magnetization
  • 2.2.2 Magnetization Curve
  • 2.2.3 Free Energy as a Function of Magnetization
  • 2.3 Rotation of Magnetization
  • 2.3.1 Stoner-Wohlfarth Model
  • 2.3.2 Stoner-Wohlfarth Diagram
  • 2.3.3 Trajectrory
  • 2.4 First-Order Phase Transitions as a Function of the Temperature
  • 2.4.1 A Model with Many Degeneracy of Zero Energy States
  • 2.4.2 Blume-Capel Model
  • 2.4.3 Spin Crossover Systems
  • 2.5 Landau Theory
  • 2.5.1 Landau Theory for Temperature Induced First-Order Phase Transition
  • 2.6 Gas-Liquid Phase Transition
  • 2.6.1 Phenomenological Method: van der Waals (vDW) Equation
  • 2.7 Statistical Treatments of the Gas-Liquid Phase Transition
  • 2.7.1 Perturbational Approach
  • 2.7.2 Lattice-Gas Model Approach
  • 2.7.3 Mean-Field Analysis for the Lattice Gas Model
  • 3 Escape Rate from the Metastable State
  • 3.1 Introduction
  • 3.2 Arrhenius Law
  • 3.3 Kramers Method
  • 3.4 Spinodal Singularity
  • 3.4.1 Master Equation for the Husimi-Temperley Model
  • 3.5 Nucleation in Model Short-Range Interaction
  • 3.6 Dynamical Spinodal Point
  • 3.7 Survival Probability of a Metastable State
  • 3.7.1 Néel-Arrhenius Process
  • 4 Spatial Pattern During the Transition
  • 4.1 Dynamics Associated with the First-Order Phase Transition
  • 4.2 Dynamics After the Temperature Quenching
  • 4.2.1 Non-conserved System: k squared tk2t Scaling
  • 4.2.2 A Stretched Exponential Law for Spin-Autocorrelation Function
  • 4.2.3 Conserved System: Lifshitz-Slyozov-Wigner Theory k cubed tk3t Scaling
  • 4.2.4 Ostwald Ripening.
  • Part II First-Order Phase Transition from Viewpoints of the Eigenvalue Problem
  • 5 Structure of Eigenvalues for the First-Order Phase Transition
  • 5.1 Transfer Matrix
  • 5.1.1 Ladder Systems
  • 5.1.2 Free Energy
  • 5.1.3 Correlation Functions
  • 5.1.4 Temperature Dependence of the Eigenvalues
  • 5.1.5 Field Dependence of the Eigenvalues Below the Critical Temperature
  • 5.2 Eigenvalue Analysis of Dynamical Processes
  • 5.2.1 Eigenstates of Master Equation
  • 5.2.2 Approach to the Stationary State
  • 5.3 Kinetic Ising Model
  • 5.3.1 Demonstration in a Small System of 2 times 22times2 System
  • 5.3.2 Master Equation for the Magnetization for a Model with Long-Range Interaction
  • 5.3.3 Relaxation times of 4 times 34times3 System
  • 5.4 Eigenvalue Problem of Quantum Master Equation
  • 5.5 Free Energy at the First-Order Phase Transition
  • 5.6 Langer's Argument
  • 5.6.1 Langer's Analysis I: A Picture of Nucleation Cluster
  • 5.6.2 Langer's Analysis II: Functional Integral
  • 5.6.3 Langer's Analysis III: A Picture of the Action
  • 5.6.4 Langer's Estimation of Decay Rate of Metastable State
  • Part III Metastability in Quantum Systems
  • 6 Collapse of Metastability by the Quantum Fluctuation
  • 6.1 Introduction
  • 6.2 Quantum Mechanical States in Double-Well Type Potential
  • 6.2.1 Chracteristics of Metastability in the Eigenstate Spectrum StartSet upper E Subscript i Baseline left parenthesis h right parenthesis EndSet{Ei(h)} as a Function of Field
  • 6.3 Characterstic of Eigenvalue Structure Around the First-Order Phase Transition
  • 6.4 Particle Conveyance by a Potential-Well
  • 6.4.1 Sudden Start by Changing the Velocity from Zero to cc
  • 6.4.2 Smooth Acceleration
  • 6.4.3 Scattering Problem
  • 6.4.4 Relaxation from Metastable Potential
  • 6.4.5 Carry Up the Particle
  • 6.5 Quantum Tunneling in Magnetic Systems.
  • 6.5.1 Metastability in Magnetic Systems
  • 6.6 Relaxation of Magnetism in Small Systems
  • 6.7 Single Molecular Magnets (SMM)
  • 6.7.1 Tunneling Under Dissipation
  • 6.7.2 Dynamics in Dissipative Environments
  • 6.8 Magnetic Foehn Effect
  • 6.9 Effect of Dissipation on the Relaxation of Metastable State
  • 6.9.1 Free-Boson Bath Model
  • 6.9.2 Dynamics of the Magnetization in Uniaxial Anisoropy
  • 6.9.3 Effects of Dissipation on the Hybridized Lowest Two States
  • 6.10 Quantum Stoner-Wohlfarth Model
  • 6.10.1 Dynamics of Magnetization
  • 6.10.2 Distribution of the Population over the States
  • 6.10.3 Dynamics of Magnetization in Dissipative Environment
  • 6.11 Nucleation in Quantum Systems
  • 6.12 Transverse-Ising Model
  • 6.12.1 Visualization of Quantum and Classical Fluctuation in a left parenthesis d plus 1 right parenthesis(d+1) Dimensional Representation of States
  • 6.13 Cooperative Phenomena in a Cavity System
  • 6.13.1 Cavity System
  • 6.13.2 Phase Transitions of the Dicke Hamiltonian
  • 6.14 Optical Bistability
  • 6.14.1 Mean-Field Analysis
  • 6.14.2 Analogy to a Picture of Thermodynamic Free Energy
  • 6.14.3 Numerical Study of the Size Dependence
  • 6.14.4 Metastability in the Bistable Region
  • 6.14.5 Hysteresis Phenomena
  • 6.15 Limit Cycle of the Hysteresis
  • 6.15.1 Dynamics Under an Driving Force with Periodically Oscillating Amplitude
  • 6.15.2 Floquet Map
  • 6.15.3 Mean-Field Analysis of Limit Cycle
  • Part IV Quantitative Estimation of Relaxation Time
  • 7 Coercivity of Magnets
  • 7.1 Introduction
  • 7.2 Coercivity Estimated by the Free Energy Landscape
  • 7.2.1 Minimum Energy Path (MEP) Method
  • 7.2.2 Free Energy Landscape Method
  • 7.3 Characteristic Quantities of Magnetization Reversal
  • 7.3.1 Activation Volume
  • 7.3.2 Magnetic Viscosity.
  • 7.3.3 Relation Between the Activation Volume upper V Subscript normal aVa and the Magnetic Viscosity upper SS
  • 7.3.4 Coercivity Obtained by a Direct Simulation of SLLG
  • 7.3.5 Coercivity of Large Grains
  • 7.4 Coercivity of Magnets as an Ensemble of Grains
  • Part V Appendices
  • 8 Appendices
  • 8.1 Brief Review on the Mean-Field Approximation
  • 8.1.1 Basic Idea of Mean-Field Theory
  • 8.1.2 Mean-Field Free Energy as a Function of the Magnetization F(m:T,H)
  • 8.1.3 Free Energy in Bragg-Williams Approximation
  • 8.1.4 Free Energy of the Long-Range Interaction Model (Husimi-Temperley Model)
  • 8.1.5 Free Energy as a Variational Function
  • 8.2 Equation of Stochastic Processes
  • 8.2.1 Master Equation and Fokker-Planck Equation
  • 8.2.2 Master Equation in Differential Form
  • 8.2.3 Symmetrization of the Time-Evolution Operator
  • 8.2.4 Master Equation for Continuous Variable
  • 8.2.5 Brownian Motion
  • 8.3 Landau-Zener Scattering
  • 8.4 Quantum Master Equation
  • 8.4.1 Lindblad Type
  • 8.4.2 Redfield Type
  • 8.4.3 Redfield Type for a Single Spin
  • 8.4.4 Bloch Equation
  • 8.4.5 Under a Time-Dependent Field
  • 8.5 Path-Integral Method
  • 8.5.1 One Particle Problem
  • 8.5.2 Partition Function at a Finite Temperature
  • 8.5.3 Onsager-Machlup Formula for Stochastic Process
  • 8.6 WKB Approximation
  • 8.6.1 Semiclassical Approximation
  • 8.6.2 Connection Formula
  • 8.6.3 Bound State
  • 8.6.4 Transmission Coefficient by WKB Approximation
  • 8.6.5 Transition Matrix
  • 8.6.6 Relaxation from Metastable Potential
  • Appendix References
  • Index.
ISBN
9789811966682 ((electronic bk.))
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