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Plastic scintillators : chemistry and applications / Matthieu Hamel, editor.
Format
Book
Language
English
Published/Created
Cham, Switzerland : Springer, [2021]
©2021
Description
1 online resource (647 pages)
Details
Subject(s)
Organic scintillators
[Browse]
Editor
Hamel, Matthieu
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Series
Topics in applied physics ; 140.
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Source of description
Description based on print version record.
Contents
Intro
Foreword
References
Preface
Contents
Contributors
Part I Materials
1 Introduction-Overview on Plastic and Inorganic Scintillators
1.1 History of Scintillators
1.2 Plastic Scintillator Chemists
1.3 The Scintillation Process in Plastics and Inorganic Materials/Crystals
1.4 Typical Preparation Process and Size Possibilities
1.5 Main Parameters and Tools for Modification or Improvement
1.5.1 Light Yield
1.5.2 Decay Time
1.5.3 Emission Wavelength
1.5.4 Behavior Against External Environment
1.5.5 Effective Atomic Number and Density
1.6 Summary
2 Neutron/Gamma Pulse Shape Discrimination in Plastics Scintillators: From Development to Commercialization
2.1 Physical Basis for Neutron/Gamma Discrimination in Organic Scintillators
2.2 Plastic Scintillators with Efficient Fast Neutron/Gamma Discrimination
2.2.1 PPO-Based PSD Plastics
2.2.2 PSD Plastics Utilizing Alternative Dyes and Dye Mixtures
2.3 PSD Plastics for Combined Detection of Fast and Thermal Neutrons
2.3.1 10B-loaded PSD Plastic Scintillators
2.3.2 6Li-loaded PSD Plastic Scintillators
2.4 Commercialization and Further Directions of Studies
3 The Detection of Slow Neutrons
3.1 Slow Neutrons: Essential Features
3.1.1 The Definition of Slow Neutrons
3.1.2 The Origins of Slow Neutrons
3.2 Nuclear Reactions of Interest in Slow Neutron Detection
3.2.1 Natural Abundance, Reaction Cross Section, Q-Value, and Typology of Reaction Products
3.2.2 Main Nuclear Reactions of Interest
3.2.3 Size of the Scintillator: Slow Neutron Mean Free Path and the Interaction of Reaction Products
3.3 Detection of Reaction Products and n/γ Discrimination
3.3.1 Background Radiation
3.3.2 Pulse Height Discrimination
3.3.3 Pulse Shape Discrimination
3.3.4 Compensated Detectors.
3.3.5 Multiplicity-Gated Detection
3.3.6 Capture-Gated Detection
3.4 Figures of Merit for Slow Neutron Detectors
3.4.1 Figures of Merit About the Response to Neutrons
3.4.2 Figures of Merit About the Response to Gamma Rays
3.4.3 Figures of Merit About the Response to Neutron Against the Response to Gamma Rays
3.5 Incorporation of Neutron Converters into Plastic Scintillator-Based Detectors
3.5.1 Homogeneous Incorporation
3.5.2 Heterogeneous Incorporation
3.6 Applications of Plastic Scintillators to the Detection of Slow Neutrons
3.6.1 Homeland Security
3.6.2 Neutron Flux Monitoring and Source Characterization
3.6.3 Reactor Antineutrino Experiments, Surveillance, and Monitoring
4 Chemical Approach on Organometallic Loading in Plastic Scintillators and Its Applications
4.1 Introduction/Context
4.1.1 Plastic Scintillation
4.1.2 Frame of This Chapter
4.1.3 Properties Optimization
4.1.4 Chemical Design and Material Science, What the Loading Implies
4.1.5 Organization of This Chapter: Application Driven
4.2 Scintillation Process Enhancement
4.2.1 Triplet Harvesting
4.2.2 Iridium Complexes
4.2.3 Europium Complexes
4.3 Photon Detection
4.3.1 Theory
4.3.2 X-ray Detection
4.3.3 Gamma Detection
4.4 Neutron Detection
4.4.1 Thermal Neutron
4.4.2 Lithium Loading
4.4.3 Boron Loading
4.4.4 Cadmium and Gadolinium Loading
4.5 Conclusion
4.6 Table by Elements
5 Polysiloxane-Based Scintillators
5.1 Foreword
5.1.1 Silicon-Based Polymer Properties: Chemistry
5.1.2 The Synthesis of Silicones
5.2 Optical Properties of Phenyl-Containing Polysiloxanes
5.3 Design of Polysiloxane-Based Scintillators
5.3.1 Energy Transfer in Organic Polymers
5.3.2 Polymeric Scintillators
5.3.3 Polysiloxane-Based Scintillators.
5.4 Polysiloxane Scintillators for Neutron Detection
5.4.1 Neutron Detection in Organic Scintillators
5.4.2 B and Li Loaded Polysiloxanes for Detection of Thermal Neutrons
5.4.3 Design of Polysiloxane Scintillators for n/γ Discrimination
5.5 Summary
6 Composite Scintillators
6.1 Introduction to Organic-Inorganic Composites
6.1.1 Overview on Fabrication Methods of Nanocomposites
6.1.2 Optical Properties Related to the Nanocomposite Structure
6.2 Plastic Scintillators Incorporating Non-emitting Inorganic Nanoparticles
6.2.1 Sol-gel-Derived Organic-Inorganic Composite Scintillators
6.2.2 Nanocomposite Scintillators Fabricated via Two-Step Synthesis
6.3 Nanocomposite Scintillators Comprising Luminescent Nanoparticles
6.3.1 Nanocomposite Scintillators Comprising Inorganic Phosphor Nanoparticles
6.3.2 Nanocomposite Scintillators Comprising Semiconductor Nanocrystals
6.4 Summary and Future Prospects
7 Molecular Design Considerations for Different Classes of Organic Scintillators
7.1 Design Considerations for Crystalline, Plastic, and Liquid Scintillators
7.1.1 Background on Scintillation Mechanisms
7.1.2 Process (1): Direct Excitation into π-Electronic States
7.1.3 Process (2): Overview of Direct Ionization and Recombination of π-states
7.1.4 Physical and Mechanical Properties of Different Classes of Organic Scintillators
7.2 Future Opportunities
8 Organic Glass Scintillators
8.1 Introduction to Organic Glass Scintillators
8.2 Glassy State of Matter
8.3 Differentiating Characteristics of Organic Molecular Glasses
8.4 Design Strategies for Stable Organic Molecular Glasses
8.4.1 Nonplanar Structures
8.4.2 Increasing Molecular Size
8.4.3 Multiple Conformations
8.4.4 Physical Mixtures.
8.5 Fluorescent Molecular Glasses as Organic Glass Scintillators (OGSs)
8.6 Organic Glass Scintillators: Case Studies
8.7 Organic Glass Thermal and Mechanical Properties
8.7.1 Mechanical Strength: Intermolecular Interactions
8.7.2 Mechanical Strength: Organic Glass/Polymer Blending
8.8 Properties of OGS/Polymer Blends
8.8.1 Effect of Small-Molecule Additives on Tg
8.8.2 Scintillation Properties of OGS/Polymer Blends
8.9 Organic Glass Scintillator Fabrication Methods
8.10 Long-Term Stability and Environmental Aging of Organic Glass Scintillators
8.10.1 Surface Versus Bulk Diffusion
8.10.2 Accelerated Aging of Organic Glasses and Mitigation Methods
8.11 Compatibility of OGS with Multi-functional Additives
8.11.1 Boron-Loaded OGS for Fast Neutron/Gamma PSD and Thermal Neutron Capture
8.11.2 Metal-Loaded OGS for Fast Neutron/Gamma PSD and Gamma-Ray Spectroscopy
8.12 Summary and Future Outlook
Part II Applications
9 Optical Improvements of Plastic Scintillators by Nanophotonics
9.1 Introduction
9.2 Enhancement of Light Extraction Efficiency of Plastic Scintillators by Photonic Crystals
9.2.1 Introduction of Photonic Crystals
9.2.2 Enhancement Mechanism of Light Extraction Efficiency by Photonic Crystals
9.2.3 Control of Directional Emission by Photonic Crystals
9.2.4 Consideration for the Structural Design of Photonic Crystals
9.3 Control of Directional Emission of Plastic Scintillators by Plasmonic Lattice Resonances
9.4 Patterning Techniques for Plastic Scintillators
9.4.1 Self-assembly Lithography
9.4.2 Nanoimprint Lithography (NIL)
9.4.3 X-Ray Interference Lithography (XIL)
9.5 Improved Scintillation Performance of Detectors by Photonic Crystals
9.6 Summary and Remark
References.
10 Analog and Digital Signal Processing for Nuclear Instrumentation
10.1 Introduction
10.2 The Light to Electric Signal Conversion
10.2.1 Design of PMTs
10.2.2 Solid-State Semiconductor Photodetectors
10.3 The Signal Acquisition Frontend
10.3.1 Charge to Voltage Conversion
10.3.2 Gain and Pulse Shaping Stage
10.3.3 Voltage Limiters
10.3.4 Impedance Matching and Other Effects
10.4 The Digitization Stage
10.4.1 Signal Digitization Basics
10.4.2 Digitizer Architectures
10.5 Signal Processing and Feature Extraction
10.5.1 Low-Level Digital Stream Processing
10.5.2 Digital Pulse Processing
10.6 Data and Information Processing
10.6.1 Count Rate Analysis
10.6.2 Discrimination of the Nature of the Interactions
10.6.3 Spectral Unmixing and Radionuclide Identification
10.7 Conclusion
11 Radioactive Noble Gas Detection and Measurement with Plastic Scintillators
11.1 Radioactive Noble Gas Isotopes
11.1.1 Kr-85
11.1.2 Xe-131m
11.1.3 Xe-133
11.1.4 Xe-133m
11.1.5 Xe-135
11.1.6 Ar-37
11.1.7 Rn-222 and Progenies
11.1.8 Rn-220 and Progenies
11.2 Application of Plastic Scintillators to the Detection of Noble Gas
11.2.1 Xenon Detection Systems for the CTBT Network
11.2.2 Kr-85 Monitors Using Plastic Scintillators
11.2.3 Radon and Thoron Detection and Measurement with Plastic Scintillators
11.3 RNG-Related Properties of Plastic Scintillators
11.3.1 Noble Gas Absorption in Plastic Materials
11.3.2 Application of Pulse Shape Discrimination to 222Rn Measurements
11.3.3 Description of the Alpha-Particle Peak Shapes in 222Rn Measurements with Plastic Scintillators
11.4 Concluding Remarks
12 Recent Advances and Clinical Applications of Plastic Scintillators in the Field of Radiation Therapy
12.1 Introduction.
12.2 Basic Dosimetry Properties of Plastic Scintillators.
Show 189 more Contents items
ISBN
3-030-73488-9
OCLC
1260344440
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