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Radical chemistry / M. John Perkins.
Author
Perkins, M. John (Michael John)
[Browse]
Format
Book
Language
English
Published/Created
New York ; London : Ellis Horwood, 1994.
Description
x, 182 pages : illustrations ; 24 cm.
Availability
Copies in the Library
Location
Call Number
Status
Location Service
Notes
Lewis Library - Stacks
QD476 .P474 1994
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Details
Subject(s)
Free radicals (Chemistry)
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Free radical reactions
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Organic compounds
—
Synthesis
[Browse]
Series
Ellis Horwood series in organic chemistry
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Bibliographic references
Includes bibliographical references (p. [159]-164) and index.
Contents
Preface
1 Introduction (starting p. 1)
2 Chain reactions and unit steps (starting p. 8)
2.2 Bimolecular processes (starting p. 10)
2.3 Unimolecular processes (starting p. 15)
2.4 An introduction to the kinetics of radical chain reactions (starting p. 19)
3 Initiation and some non-chain processes: "free" and "caged" radicals (starting p. 21)
3.1 Thermolysis (starting p. 21)
3.2 Photolysis (starting p. 29)
3.3 Radiolysis (starting p. 29)
3.4 Electron transfer and molecule-induced homolysis (starting p. 30)
4 An introduction to reactivity and selectivity in radical reactions (starting p. 33)
4.2 Halogenation of alkanes (starting p. 34)
4.3 Other reactions (starting p. 39)
4.4 Stereoelectronic effects (starting p. 41)
4.5 Polar influences (starting p. 42)
4.6 Steric effects (starting p. 47)
4.7 Intra- versus inter-molecular reactions (starting p. 48)
4.8 Radical addition versus hydrogen atom transfer (starting p. 50)
4.9 Summary (starting p. 51)
5 Detection of organic free radicals, and a discussion of their structures (starting p. 52)
5.2 ESR spectroscopy (starting p. 53)
5.3 ESR and radical structure (starting p. 59)
5.4 Spin trapping (starting p. 63)
5.5 Electron nuclear double resonance spectroscopy (starting p. 69)
5.6 Chemically induced dynamic nuclear polarisation (CIDNP) (starting p. 70)
6 Radicals and radical reactions in organic synthesis (starting p. 74)
6.2 Chain reactions in synthesis (starting p. 75)
6.3 Non-chain processes (starting p. 90)
7 Some stereochemical considerations (starting p. 96)
8 Radical ions and electron transfer (starting p. 102)
9 Some special topics (starting p. 112)
9.1 Frontier orbital approach to radical reactivity (starting p. 112)
9.2 Radical kinetics and thermodynamics (starting p. 115)
9.3 Captodative stabilisation (starting p. 117)
9.4 Autoxidation of unsaturated lipids (starting p. 118)
9.5 Antioxidants (starting p. 122)
9.6 Adamantane matrix studies (starting p. 123)
9.7 Thermolysis of dibenzoyl peroxide in benzene (starting p. 124)
9.8 Stable-radical effects (starting p. 127)
9.9 Radicals from ketone photochemistry (starting p. 128)
9.10 Transition-metal ions in radical reactions (starting p. 129)
10 Radicals in biology (starting p. 132)
10.1 Oxidising radicals (starting p. 132)
10.2 Enzyme catalysis mechanisms (starting p. 139)
10.3 Spin trapping and spin labelling (starting p. 147)
10.4 The enediyne antibiotics (starting p. 151)
Appendix: Absolute rate constants of unit steps in radical chemistry (starting p. 154)
Selected additional reading and bibliography (starting p. 159)
Problems (starting p. 165)
Subject index (starting p. 176)
Show 48 more Contents items
ISBN
0133209202 ((pbk.))
9780133209204 ((pbk.))
LCCN
95176205
OCLC
31608655
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Radical chemistry / M. John Perkins.
id
SCSB-8561761
Radical chemistry / M. John Perkins.
id
SCSB-3223205